๐ Identification of phosphorylation sites in the nucleocapsid protein (N protein) of SARS-coronavirus
After decoding the genome of SARS-coronavirus (SARS-CoV), next challenge is to understand how this virus causes the illness at molecular bases. Of the viral structural proteins, the N protein plays a pivot role in assembly process of viral particles as well as viral replication and transcription. The SARS-CoV N proteins expressed in the eukaryotes, such as yeast and HEK293 cells, appeared in the multiple spots on two-dimensional electrophoresis (2DE), whereas the proteins expressed in E. coli showed a single 2DE spot. These 2DE spots were further examined by Western blot and MALDI-TOF/TOF MS, and identified as the N proteins with differently apparent pI values and similar molecular mass of 50 kDa. In the light of the observations and other evidences, a hypothesis was postulated that the SARS-CoV N protein could be phosphorylated in eukaryotes. To locate the plausible regions of phosphorylation in the N protein, two truncated N proteins were generated in E. coli and treated with PKCฮฑ. The two truncated N proteins after incubation of PKCฮฑ exhibited the differently electrophoretic behaviors on 2DE, suggesting that the region of 1-256 aa in the N protein was the possible target for PKCฮฑ phosphorylation. Moreover, the SARS-CoV N protein expressed in yeast were partially digested with trypsin and carefully analyzed by MALDI-TOF/TOF MS. In contrast to the completely tryptic digestion, these partially digested fragments generated two new peptide mass signals with neutral loss, and MS/MS analysis revealed two phosphorylated peptides located at the "dense serine" island in the N protein with amino acid sequences, GFYAEGSRGGSQASSRSSSR and GNSGNSTPGSSRGNSPARMASGGGK. With the PKCฮฑ phosphorylation treatment and the partially tryptic digestion, the N protein expressed in E. coli released the same peptides as observed in yeast cells. Thus, this investigation provided the preliminary data to determine the phosphorylation sites in the SARS-CoV N protein, and partially clarified the argument regarding the phosphorylation possibility of the N protein during the infection process of SARS-CoV to human host.
keywords
๐ acid sequence (108)
๐ amino acid (454)
๐ acid sequences (44)
๐ viral particles (45)
๐ structural proteins (197)
๐ viral replication (258)
author
๐ค Lin, Liang
๐ค Shao, Jianmin
๐ค Sun, Maomao
๐ค Liu, Jinxiu
๐ค Xu, Gongjin
๐ค Zhang, Xumin
๐ค Xu, Ningzhi
๐ค Wang, Rong
๐ค Liu, Siqi
year
โฐ 2007
issn
๐ 13873806
volume
268
number
2-3
page
296-303
citedbycount
2
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